Angelina Jolie for Louis Vuitton "Core Values" ad campaign

Angelina Jolie is the latest star to pose for Louis Vuitton's "Core Values" ad campaign. A serene and sultry Angie (in her own clothes!) gazes off into the distance in Cambodia's Siem Reap province, a Louis Vuitton bag hanging off her shoulder. This ad was shot by world famous photographer Annie Leibovitz.

The Cambodian setting and "mother earth" vibe (Jolie wears natural makeup and her own clothes) is fitting for the actress, who found time in between making all those movies and adopting all those children to advocate for Cambodia on the international stage.

The "Core Values" ads, set to run for 18 months, will feature other celeb-humanitarians such as Bono. Curiously, the logo tote slung over Jolie's arm, Louis Vuitton's Alto bag, is a discontinued style. But Vuitton's executive vice president Pietro Beccari told WWD, "We are considering to re-edit it." Smart move.